淮北芦岭矿区土壤中PAHs的分布特征及分析

doi:10.3969/j.issn.0253-2778.2010.07.001

中国科学技术大学学报 ›› 2010, Vol. 40 ›› Issue (7): 661-666.DOI: 10.3969/j.issn.0253-2778.2010.07.001

• 原创论文 • 下一篇

淮北芦岭矿区土壤中PAHs的分布特征及分析

刘静静

中国科学院壳幔物质与环境重点实验室，中国科学技术大学地球与空间科学学院，安徽合肥 230026

收稿日期:2009-12-03 修回日期:2010-02-08 出版日期:2010-07-31 发布日期:2010-07-31
通讯作者: 刘桂建
作者简介:刘静静，女，1985年生，硕士生. 研究方向：有机物环境化学. E-mail: Ljjfei@mail.ustc.edu.cn
基金资助:
国家自然科学基金（40873070），国家科技重大专项（2008ZX05039-003）和安徽省优秀青年基金（08040106909）资助.

Concentrations, distributions, and source of polycyclic aromatic hydrocarbons in soil of Luling Coal Mine in Huaibei

LIU Jingjing

CAS Key Laboratory of Crust-Mantle Materials and Environment, School of Earth and Space Sciences, University of Science and Technology of China, Hefei 230026, China

Received:2009-12-03 Revised:2010-02-08 Online:2010-07-31 Published:2010-07-31

摘要/Abstract

摘要： 在运用气相色谱-质谱方法对淮北芦岭煤矿区17个代表性土壤样品和一个煤矸石样品进行28种PAHs（polycyclic aromatic hydrocarbons）测试和分析的基础上，研究了PAHs在矿区土壤中的分布特征及迁移行为，评价了PAHs在矿区的环境影响.结果表明，研究区28种PAHs，总含量(干重)∑28PAHs从035 μg/g到621 μg/g，平均值为169 μg/g.其中16种是USEPA规定的优控PAHs，总含量（干重）∑16PAHs从023 μg/g到353 μg/g，平均值为100 μg/g.按相关评价标准，该区部分土壤受到PAHs中度到重度污染,且该区PAHs污染来源是煤矸石堆和生物质燃料燃烧.通过毒性评价可知，PAHs污染土壤的环境风险主要是苯并[a]芘，TEQ达6068%.

关键词: 芦岭矿区, 土壤, PAHs（polycyclic aromatic hydrocarbons）, 来源

Abstract: 17 representative soil samples and 1 coal slack sample were collected in the surroundings of Luling Coal Mine in Huaibei Province, China. The concentrations of polycyclic aromatic hydrocarbons (PAHs) in the collected samples were detemined by gas chromatography equipped with a mass spectrometry detector (GC-MS). The distribution and transportation behavior of PAHs were analyzed and the environmental impact of the PAHs in the soil of the coal mine was further evaluated. The results showed that the concentrations of 28 PAHs in the collected soil samples ranged from 035 to 621 μg/g, with an average concentration of 169 μg/g, among which 16 PAHs are USEPA priority PAHs. The total contents of these 16 PAHs ranged from 023 to 353 μg/g, with the average contents being 100 μg/g. Compared with the relevant standards of organic pollutants in the soil, these typical regions were moderately or highly polluted according to the concentrations of ∑16PAHs. It was further discovered that the sources of PAHs were gob piles and combustion of biomass. A toxicity assessment indicates that the environmental risks for PAHs are mainly BghiP whoseTEQ accounts for 6068% of the total value.

Key words: Luling Coal Mine, soil, polycyclic aromatic hydrocarbons (PAHs), sources

刘静静，王儒威，刘桂建，张佳妹. 淮北芦岭矿区土壤中PAHs的分布特征及分析[J]. 中国科学技术大学学报, 2010, 40(7): 661-666.

LIU Jingjing, WANG Ruwei, LIU Guijian, ZHANG Jiamei. Concentrations, distributions, and source of polycyclic aromatic hydrocarbons in soil of Luling Coal Mine in Huaibei[J]. Journal of University of Science and Technology of China, 2010, 40(7): 661-666.

[1]	孙浩，周春财，徐仲雨，王兴明，刘桂建. 淮北矿区土壤重金属空间分布与环境评价[J]. 中国科学技术大学学报, 2018, 48(7): 560-566.
[2]	秦先燕，彭苗枝，胡波，吴剑雄，孙跃. 巢湖北部土壤重金属污染特征及生态风险评价[J]. 中国科学技术大学学报, 2017, 47(5): 426-434.
[3]	魏勇，周春财，王婕，范支柬，刘桂建，. 淮南矿区土壤中6种典型微量元素的空间分布特征及其生态风险评价[J]. 中国科学技术大学学报, 2017, 47(5): 413-420.
[4]	陈辉，郑刘根，程桦，姜春露，陈永春. 淮南顾桥采煤沉陷区土壤中镉的赋存特征及其生物有效性[J]. 中国科学技术大学学报, 2015, 45(5): 388-396.
[5]	黄方，南晓云. 土壤中非传统稳定同位素研究进展[J]. 中国科学技术大学学报, 2015, 45(2): 87-100.
[6]	卢岚岚，刘桂建，王兴明，王婕. 淮南顾桥矿土壤环境中微量元素的分布及其生态风险评价[J]. 中国科学技术大学学报, 2014, 44(2): 119-127.
[7]	赵丽，王张民，黄阳，袁林喜，尹雪斌. 土壤追施锌肥对水稻植株锌累积特征影响研究[J]. 中国科学技术大学学报, 2013, 43(8): 631-638.

淮北芦岭矿区土壤中PAHs的分布特征及分析

Concentrations, distributions, and source of polycyclic aromatic hydrocarbons in soil of Luling Coal Mine in Huaibei

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 7

编辑推荐

Metrics

本文评价