中国科学技术大学学报 ›› 2010, Vol. 40 ›› Issue (7): 667-672.DOI: 10.3969/j.issn.0253-2778.2010.07.002

• 原创论文 • 上一篇    下一篇

有机碳对地下含水层中硝酸盐去除影响实验研究

王志平   

  1. 合肥工业大学资源与环境工程学院,安徽合肥 230009
  • 收稿日期:2009-11-16 修回日期:2010-03-10 出版日期:2010-07-31 发布日期:2010-07-31
  • 通讯作者: 孙世群
  • 作者简介:王志平,女,1985年生,硕士生. 研究方向:环境科学和地下水模拟. E-mail: wangzhiping1985825@163.com
  • 基金资助:
    国家自然科学基金(40672154;40872166)和新世纪优秀人才计划项目(NCET-06-0541)资助.

Effect of organic carbon on nitrate removal in groundwater

WANG Zhiping   

  1. Hefei University of Technology, Hefei 230009, China
  • Received:2009-11-16 Revised:2010-03-10 Online:2010-07-31 Published:2010-07-31

摘要: 地下水中硝酸盐污染严重,采用室内试验装置,研究了以芦苇秸秆为碳源去除地下水中的硝酸盐的影响因素和效果,并探讨NO-2-N的积累规律.研究表明:①在反硝化过程中,总有机碳TOC与NO-3-N之间存在负相关性,而NO-3-N与HCO-3之间存在一定的负相关性;②要使处理后地下水中NO-3-N满足质量标准20 mg·L-1,出水TOC浓度需达到一定值;③实验中当出水C/N小于1时NO-2-N开始出现积累,NO-2-N积累与出水C/N之间满足一定的规律;最佳C/N约为1,可以同时满足出水NO-3-N、TOC、NO-2-N的要求.

关键词: 有机碳, 地下水, 硝酸盐, C/N

Abstract: The factors influential on nitrate removal in groundwater were studied in laboratory equipment containing unprocessed reed stalks and sand and the rule governing nitrite accumulation was found. The results showed that: ①Negative correlation existed between the TOC and NO-3-N, while negative correlation existed between the NO-3-N and HCO-3. ②Some TOC was demanded if the NO-3-N was to meet the quality standards(20 mg·L-1). ③Nitrite accumulated when the C/N ratios were less than 1.00 and there were some rules between nitrite accumulation and C/N ratios. The optimal C/N ratio was assumed to be 100, at which more removal of NO-3-N is achieved with less excess TOC and NO-2-N in the effluent.

Key words: organic carbon, groundwater, nitrate, C/N