拉应力下T91钢在550 ℃液态铅铋中的腐蚀行为

doi:10.3969/j.issn.0253-2778.2018.05.006

中国科学技术大学学报 ›› 2018, Vol. 48 ›› Issue (5): 378-384.DOI: 10.3969/j.issn.0253-2778.2018.05.006

拉应力下T91钢在550 ℃液态铅铋中的腐蚀行为

胡亚东，罗林，姜志忠，李春京，陈建伟

1.中国科学院核能安全技术研究所中子输运理论与辐射安全重点实验室，安徽合肥 230031； 2. 中国科学技术大学，安徽合肥 230026

收稿日期:2017-12-19 修回日期:2018-03-08 接受日期:2018-03-08 出版日期:2018-05-31 发布日期:2018-03-08
通讯作者: 罗林
作者简介:胡亚东，男，1991年生，硕士. 研究方向: 反应堆材料腐蚀与防护. E-mail: huyd@mail.ustc.edu.cn
基金资助:
国家自然科学基金(51501185, 51401204, 51501184),安徽省自然科学基金（1708085QE96）资助.

Corrosion behavior of T91 steel in liquid lead-bismuth eutectic at 550 ℃ under different tensile stresses

HU Yadong, LUO Lin, JIANG Zhizhong, LI Chunjing, CHEN Jianwei

1. Key Laboratory of Neutronics and Radiation Safety, Institute of Nuclear Energy Safety Technology, Chinese Academy of Sciences,Hefei 230031, China; 2. University of Science and Technology of China, Hefei 230026, China

Received:2017-12-19 Revised:2018-03-08 Accepted:2018-03-08 Online:2018-05-31 Published:2018-03-08

摘要/Abstract

摘要： 为有效评估T91钢在液态铅铋合金（lead-bismuth eutectic, LBE）中不同拉应力下的腐蚀行为，采用小锥度圆锥体试样，开展了0~180 MPa下T91钢在550 ℃、1×10-6 wt%氧浓度LBE中的腐蚀实验.结果表明：(Fe,Cr)3O4层和内氧化层始终存在，而Fe3O4层在拉应力作用下出现严重的脱落，且Fe3O4碎片随应力增加而变小；(Fe,Cr)3O4层由于Cr富集度不同而呈现出两层亚结构；随着拉应力的增加，裂纹数量增加，尺寸变大，并不断向基体方向扩展，到180 MPa时已贯穿整个(Fe,Cr)3O4层.此外，各氧化层厚度随应力增加而增加，但增厚速率不断降低.

关键词: 铅铋合金, T91, 腐蚀, 氧化层, 拉应力

Abstract: To efficiently evaluate the corrosion behavior of T91 steel in lead-bismuth eutectic (LBE) under different stresses, a corrosion experiment of small tapered conical specimen of T91 in LBE with an oxygen concentration of 1×10-6 wt% at 550 ℃ under 0~180 MPa was carried out. The results showed that the (Fe,Cr)3O4 and internal oxidation zone always exist, but the Fe3O4 peels off severely under tensile stress, and its fragments become smaller with the increase of stress; (Fe,Cr)3O4 has two sub-layers, which is caused by different Cr enrichments; As the tensile stress increases, the cracks increase in number and size, extending continuously to the matrix direction, running through the whole (Fe,Cr)3O4 by the time the tensile stress reaches 180 MPa. Moreover, with the tensile stress increasing, the thickness of each oxide layer increases, but the rate of incrassation decreases constantly.

Key words: lead-bismuth eutectic, T91, corrosion, oxide layer, tensile stress

中图分类号:

TL34

胡亚东，罗林，姜志忠，李春京，陈建伟. 拉应力下T91钢在550 ℃液态铅铋中的腐蚀行为[J]. 中国科学技术大学学报, 2018, 48(5): 378-384.

HU Yadong, LUO Lin, JIANG Zhizhong, LI Chunjing, CHEN Jianwei. Corrosion behavior of T91 steel in liquid lead-bismuth eutectic at 550 ℃ under different tensile stresses[J]. Journal of University of Science and Technology of China, 2018, 48(5): 378-384.

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拉应力下T91钢在550 ℃液态铅铋中的腐蚀行为

Corrosion behavior of T91 steel in liquid lead-bismuth eutectic at 550 ℃ under different tensile stresses

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