中国科学技术大学学报 ›› 2014, Vol. 44 ›› Issue (11): 926-932.DOI: 10.3969/j.issn.0253-2778.2014.11.007

• 原创论文 • 上一篇    下一篇

淮南采煤沉陷水体中氮磷的分布特征及环境意义

刘响响   

  1. 1.安徽大学资源与环境工程学院,矿山环境修复与湿地生态安全协同创新中心,安徽合肥 230601; 2.煤矿生态环境保护国家工程实验室,安徽淮南 232001
  • 收稿日期:2014-05-22 修回日期:2014-08-26 出版日期:2014-11-30 发布日期:2014-11-30
  • 通讯作者: 郑刘根
  • 作者简介:刘响响,男,1989年生,硕士生. 研究方向:环境科学与工程. E-mail:xxliu86@163.com
  • 基金资助:
    “十二五”国家科技支撑计划(2012BAC10B02),国家自然科学基金(41373108),煤矿生态环境保护国家工程实验室科技攻关项目(HKKY-JT-JS2012),安徽省自然科学基金(1208085ME66),安徽省教育厅重点基金(KJ2012A022)资助.

Distribution characteristics and environmental significance of nitrogen and phosphorus in the Huainan coal mining subsidence area

LIU Xiangxiang   

  1. 1.School of Resource and Environment Engineering, Collaborative Innovation Center for Mines Environmental Remediation and Wetland Ecological Security, Anhui University, Hefei 230601, China; 2.National Engineering Laboratory of Coal Mine Ecological Environment Protection, Huainan 232001, China
  • Received:2014-05-22 Revised:2014-08-26 Online:2014-11-30 Published:2014-11-30

摘要: 煤炭资源的大规模开采,导致高潜水位采煤沉陷区积水面积迅速扩展.以淮南市7个矿区典型的采煤沉陷水体为研究对象,测试分析了水体中氮、磷等水质指标并进行了水质评价.结果表明:①研究区沉陷水塘的总氮(TN)、氨氮(NH4+-N)、硝态氮(NO3--N)与总磷(TP)的平均值分别是304,061,061和016 mg/L,水体的氮磷负荷较为严重;②沉陷区水体中TN分布为新庄孜矿(558 mg/L)>潘一矿(407 mg/L)>顾桥矿(277 mg/L)>潘三矿(179 mg/L)>朱集和潘北矿(147 mg/L)>潘二矿(117 mg/L),TP分布为潘三矿(029 mg/L)>新庄孜和朱集矿(020 mg/L)>顾桥矿(017 mg/L)>潘北矿(014 mg/L)>潘一矿(011 mg/L)>潘二矿(005 mg/L),TN分布与沉陷时间具有良好相关性,而TP分布没有明显规律;③沉陷区的TN和TP相关性不显著,TN和NH4+-N具有良好的正相关,温度、溶解氧、pH与氮磷指标具有一定的相关性,综合水质标识法评价结果显示,研究区水体中的氮磷水平基本处于Ⅲ类或者超过Ⅲ类水,水体中最主要的超标和污染因子是TN,其次是NH4+-N.

关键词: 淮南, 采煤沉陷水体, 氮磷, 分布特征, 综合水质标识指数法, 环境意义

Abstract: With extensive coal mining, the water coverage of coal mining subsidence areas tends to expand rapidly. Seven typical subsidence water areas in Huainan mining area were selected. Then their water quality indicators were measured, which included total nitrogen (TN), total phosphorus (TP), ammonia nitrogen (NH4+-N), nitrate nitrogen (NO3--N), etc., and the water quality was assessed. The results show that: ① the mean contents of TN, NH4+-N, NO3--N and TP are 304, 061, 061 and 016 mg/L, respectively. The nitrogen and phosphorus load was serious in the studied area. ② The distributions of TN in Huainan coal mining subsidence area are: Xinzhuangzi (558 mg/L)>Panyi (407 mg/L)>Guqiao (277 mg/L)>Pansan (179 mg/L)>Zhuji and Panbei (147 mg/L)>Paner (117 mg/L). The distributions of TP are: Pansan (029 mg/L)>Xinzhuangzi and Zhuji (020 mg/L)>Guqiao (017 mg/L)>Panbei (014 mg/L)>Panyi (011 mg/L)>Paner (005 mg/L). The distribution of TN and subsidence time show good positive correlation, while there is no obvious regularity in the distribution of TP. ③ Data analysis indicates that TN and NH4+-N have good positive correlation. Temperature, dissolved oxygen, pH have some correlation with nitrogen and phosphorus, respectively. The evaluation results of the comprehensive water quality identification method show that the concentration of nitrogen and phosphorus is basically at level Ⅲ or below in the water quality standards, and the most important pollution factor is TN, followed by NH4+-N.

Key words: Huainan, coalmine subsidence water, nitrogen and phosphorus, spatial distribution, comprehensive water quality identification index, environmental significance