中国科学技术大学学报 ›› 2021, Vol. 51 ›› Issue (2): 87-102.DOI: 10.52396/JUST-2021-0045

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用于电催化水分解的三维阵列材料

刘启龙1, 肖翀1,2*   

  1. 1.合肥综合性国家科学中心能源研究院,安徽合肥 230031;
    2.合肥微尺度物质科学国家研究中心,安徽合肥 230026
  • 收稿日期:2021-02-06 修回日期:2021-02-22 出版日期:2021-02-28 发布日期:2021-11-16
  • 通讯作者: * E-mail:cxiao@ustc.edu.cn

Three-dimensional array materials for electrocatalytic water splitting

Liu Qilong1, Xiao Chong1,2*   

  1. 1. Institute of Energy, Hefei Comprehensive National Science Center, Hefei 230031, China;
    2. Hefei National Laboratory for Physical Sciences at the Microscale, Hefei 230026, China
  • Received:2021-02-06 Revised:2021-02-22 Online:2021-02-28 Published:2021-11-16
  • Contact: * E-mail: cxiao@ustc.edu.cn

摘要: 氢能源被认为是最有可能替代化石燃料的清洁能源之一.探索适用于水分解产氢的催化剂已经成为电解水领域的重要课题.由于纳米粉体材料导电性不好,且在催化过程中容易堆积,所以将纳米活性物质和导电基底结合起来,构建具有开放多孔结构的三维(3D)阵列电极已经成为电催化领域的研究热点.本文首先总结了3D阵列电极在电催化水分解中的优势,然后介绍了提高材料催化性能的几种策略,最后对用于水分解的阵列催化材料进行了分类和总结,希望能为新的电催化材料的设计和制备提供参考.

关键词: 电催化水分解, 氢能源, 3D阵列电极

Abstract: Hydrogen energy is considered to be one of the clean energy sources most likely to alternate fossil fuels. The exploration of catalytic materials suitable for electrocatalytic water splitting to produce hydrogen has become an important subject in the field of water electrolysis. Limited to the phenomena of easy stacking of nano-powder materials and poor conductivity during the catalytic reaction, the combination of nano-active materials and conductive substrates to construct three-dimensional (3D) array electrodes with open porous structures has become a research hotspot. This article first summarizes the advantages of 3D array electrodes for water electrolysis, then briefly describes several strategies for improving the catalytic performance of materials, and finally classifies and summarizes the array catalytic materials used for water electrolysis. It is expected to provide reference for the design and synthesis of electrocatalytic materials in the future.

Key words: electrocatalytic water splitting, hydrogen energy, 3D array electrode

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