Journal of University of Science and Technology of China ›› 2011, Vol. 41 ›› Issue (10): 867-871.DOI: 10.3969/j.issn.0253-2778.2011.10.004

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Growth and characterization of Gd2O3 thin film on Si

LI Tingting   

  1. 1.National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029, China; 2.School of Nuclear Science and Technology, University of Science and Technology of China, Hefei 230029, China; 3.Department of Physics, University of Science and Technology of China, Hefei 230026, China
  • Received:2010-01-24 Revised:2010-05-05 Online:2011-10-31 Published:2011-10-31
  • Contact: QI Zeming
  • About author:LI Tingting, female, born in 1983, master. Research field: high-k gate dielectric film. E-mail: tingli@mail.ustc.edu.cn

Abstract: Gd2O3 thin films were deposited on Si (100) substrates by pulsed laser deposition (PLD). The structure, composition and band offset were investigated by X-ray diffraction (XRD), X-ray reflectivity (XRR), X-ray photoelectron spectroscopy (XPS) and ultraviolet photoemission spectroscopy (UPS). The results show that, the Gd2O3 thin film is amorphous when growing at 300 ℃ and is crystallized into monoclinic structure at 650 ℃. The formation of Gd-silicate interfacial layer due to interface reaction is confirmed by XRR and XPS. The valence band offset (ΔEV) of (-228±01)eV is obtained by XPS.

Key words: Gd2O3 thin film, pulsed laser deposition, high gate dielectric constant