Investigation on morphology control  of the nanoporous nickel phosphate

doi:10.3969/j.issn.0253-2778.2016.12.007

Journal of University of Science and Technology of China ›› 2016, Vol. 46 ›› Issue (12): 1007-1014.DOI: 10.3969/j.issn.0253-2778.2016.12.007

• Original Paper • Previous Articles

Investigation on morphology control of the nanoporous nickel phosphate

NIE Shibin, DONG Xiang, ZHANG Chi, ZHOU Can, HU Yuan

1.Key Laboratory of Safe and Effective Coal Mining of Ministry of Education, School of Energy Resources and Safety, Anhui University of Science and Technology, Huainan 232001, China; 2.State Key Laboratory of Fire Science, University of Science and Technology of China, Hefei 230026, China

Received:2016-04-12 Revised:2016-07-22 Accepted:2016-07-22 Online:2016-07-22 Published:2016-07-22
Contact: NIE Shibin
About author:NIE Shibin (corresponding author), male, born in 1983, PhD/associate professor. Research field: flame retardant polymer composites. E-mail：nsb@mail.ustc.edu.cn
Supported by:
Supported by National Natural Science Foundation of China(51303004,U1332134)，PhD Programs Foundation of Ministry of Education of China (20133415120001).

Abstract

Abstract: VSB-1 was synthesized by hydrothermal method in various synthesis conditions, and the influences of the synthesis conditions on the morphology of VSB-1 were studied. The results show that by adjusting the synthesis conditions, different morphologies of VSB-1 can be obtained. The morphology of VSB-1 changes from a needle-like to mushroom-like shape and the diameter of the VSB-1 also varies. The morphologies influence the surface areas of VSB-1.The needle-like VSB-1 has a higher BET (Brunauer-Emmet-Teller) surface than that of mushroom-like VSB-1. Meanwhile , the results show that VSB-1 has high thermal stability.

Key words: nanoporous nickel phosphate, morphology, VSB-1, hydrothermal method

CLC Number:

X932
O611.

NIE Shibin, DONG Xiang, ZHANG Chi, ZHOU Can, HU Yuan. Investigation on morphology control of the nanoporous nickel phosphate[J]. Journal of University of Science and Technology of China, 2016, 46(12): 1007-1014.

References

[1] FREY G, CHEETHAM A K. Prospects for giant pores[J]. Science,1999, 283(5405): 1 125-1 126 .
[2] LIN R H, DING Y J. A review on the synthesis and applications of mesostructured transition metal phosphates[J]. Materials, 2013, 6(1): 217-243.
[3] CHEETHAM A K, FREY G, LOISEAU T. Open-framework inorganic materials[J]. Angewandte Chemie International Edition,1999, 38(22):3 268-3 292.
[4] FORSTER P M, ECKERT J, CHANG J S, et al. Hydrogen adsorption in nanoporous nickel(II) phosphates[J]. Journal of the American Chemical Society ,2003,125(5): 1 309-1 312.
[5] GUILLOU N, GAO Q M, NOGUES M, et al. Zeolitic and magnetic properties of a 24-membered ring porousnickel(ll) phosphate, VSB-1[J]. Comptes Rendus de lAcadémie des Sciences-Series II C - Chemistry,1999,2(7/8): 387-392.
[6] CHANG J S, PARK S E, GAO Q M, et al. Catalytic conversion of butadiene to ethylbenzene over the nanoporous nickel(II) phosphate, VSB-1[J]. Chemical Communications,2001, 9(9): 859-860.
[7] TIMOFEEVA M N, PANCHENKO V N, HASAN Z, et al. Catalytic potential of the wonderful chameleons: Nickel phosphate molecular sieves[J]. Applied Catalysis A: General,2013, 455: 71-85.
[8] NIE S B, ZHANG C, PENG C, et al. Study of the synergistic effect of nanoporous nickel phosphates on novel intumescent flame retardant polypropylene composites[J]. Journal of Spectroscopy,2015, 2015:289298.
[9] NIE S B, HU Y, SONG L, et al. Study on a novel and efficient flame retardant synergist-nanoporous nickel phosphates VSB-1 with intumescent flame retardants in polypropylene[J]. Polymers for Advanced Technologies,2008, 19(6): 489-495.
[10] WU H Y, LIU M, TAN W, et al. Effect of ZSM-5 zeolite morphology on the catalytic performance of the alkylation of toluene with methanol[J]. Journal of Energy Chemistry,2014, 23(4): 491-497.
[11] LEE H J, KIM S H, KIM J H, et al.Synthesis and characterization of zeolites MTT and MFI, with controlled morphologies using mixed structure directing agents[J]. Microporous and Mesoporous Materials,2014, 195: 205-215.
[12] JHUNG S H, YOON J W, HWANG Y K, et al. Morphology control of the nanoporous nickel phosphate VSB-5 from large crystals to nanocrystals[J]. Microporous and Mesoporous Materials,2006, 89: 9-15.

（上接第992页）

[2] CHEN C, LIU G. Effects of axial guiding magnetic field on microwave power of backward-wave oscillators[J]. High Power Laser and Particle Beams, 2000, 12: 745-748.
[3] CHEN C, LIU G, HUANG W, et al. A repetitive X-band relativistic backward-wave oscillator[J]. IEEE Trans Plasma Sci, 2000, 25: 1 108-1 111.
[4] REN Y, WANG F, CHEN W, et al. Development of a superconducting magnet system for microwave application[J]. IEEE Trans Appl Supercond, 2010, 20(3): 1 912-1 915.
[5] LVOVSKY Y, STAUTNER W, ZHANG T. Novel technologies and configurations of superconducting magnets for MRI[J]. Supercond Sci Technol, 2013, 26(9): 093001.
[6] HIROSE R, KAMIKADO T, OKUI Y, et al. Development of 7 T cryogen-free superconducting magnet for gyrotron[J]. IEEE Trans Appl Supercond, 2008, 12: 920-923.
[7] WANG Q, DAI Y, ZHAO B, et al. Design of superconducting magnet for background magnetic field[J]. IEEE Trans Appl Supercond, 2008, 18(2): 548-551.
[8] CHOI Y S, KIM D L, LEE B S, et al. Conduction-cooled superconducting magnet for material control application[J]. IEEE Trans Appl Supercond, 2009, 19(3): 2 190-2 193.
[9] ZHANG X, REN Y, WANG F, et al. Development of a superconducting magnet system with zero liquid helium boil-off[J]. J Supercond Novel Magn, 2014, 27(4): 1 027-1 030.
[10] YAMASHITA T, NISHIJIMA S, TAKAHATA K, et al. Instability of impregnated windings induced by epoxy cracking[J]. IEEE Trans Magn, 1989, 25(2): 1 524-1 527.
[11] WANG Q, DAI Y, ZHAO B, et al. Development of large-bore superconducting magnet with zero-vapor liquid helium[J]. IEEE Trans Appl Supercond, 2008, 18: 787-790.
[12] CHEN P, DAI Y, WANG Q, et al. Mechanical behavior analysis of a 1 MJ SEMS magnet[J]. IEEE Trans Appl Supercond, 2010, 20(3): 1 916-1 919.

Investigation on morphology control of the nanoporous nickel phosphate

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 3

Recommended Articles

Metrics

Comments

[1]	LIAN Guofu, ZHANG Hao, CHEN Changrong, HUANG Xu, JIANG Jibin. Study on the effect of laser cladding Ni35A + TiC composite cladding morphology and forming efficiency [J]. Journal of University of Science and Technology of China, 2020, 50(6): 715-725.
[2]	YU Xiangru, DING Jianpei, LI Jinping. Tire impurity defect detection based on morphology and projection histogram [J]. Journal of University of Science and Technology of China, 2019, 49(1): 49-54.
[3]	CHEN Yao, MEI Tao*, WANG Xiaojie, LI Feng, LIU Yanwei. A bridge crack image detection and classification method based on a climbing robot [J]. Journal of University of Science and Technology of China, 2016, 46(9): 788-796.