[1] RAGAUSKAS A J, WILLIAMS C K, DAVISON B H, et al. The path forward for biofuels and biomaterials[J]. Science, 2006, 311: 484-489. [2] INKINEN S, HAKKARAINEN M, ALBERTSSONA C, et al. From lactic acid to poly(lactic acid) (PLA): Characterization and analysis of PLA and its precursors[J]. Biomacromolecules, 2011, 12: 523-532. [3] STANFORD M J, DOVEA P. Stereocontrolled ring-opening polymerisation of lactide[J]. Chem Soc Rev, 2010, 39: 486-494. [4] AJELLAL N, CARPENTIER JF, GUILLAUME C, et al. Metal-catalyzed immortal ring opening polymerization of lactones, lactides and cyclic carbonates[J]. Dalton Trans, 2010, 39: 8363-8376. [5] DIJKSTRA P J, DU H, FEIJENJ. Single site catalysts for stereoselective ring-opening polymerization of lactides[J]. Polym Chem, 2011, 2: 520-527. [6] DOVE A P, GIBSON V C, MARSHALL E L, et al. A well defined tin(II) initiator for the living polymerisation of lactide[J]. Chem Commun, 2001,3(3): 283-284. [7] NIMITSIRIWAT N, GIBSON V C, MARSHALL E L, et al. tert-Butylamidinate tin(II) complexes: High activity, single-site initiators for the controlled production of polylactide[J]. Dalton Trans, 2007, 251(39):4464-4471. [8] WANG L, POIRIER V, GHIOTTO F, et al. Kinetic analysis of the immortal ring-opening polymerization of cyclic esters: A case study with Ti (II) catalysts[J]. Macromolecules, 2014, 47: 2574-2584. [9] O'KEEFE B J, MONNIER S M, HILLMYERM A, et al. Rapid and controlled polymerization of lactide by structurally characterized ferric alkoxides[J]. J Am Chem Soc, 2001, 123: 339-340. [10] BIERNESSER A B, DELLE CHIAIE K R, CURLEY JB, et al. Block copolymerization of lactide and an epoxide facilitated by a redox switchable iron-based catalyst[J]. Angew Chem Int Ed, 2016, 55: 5251-5254. [11] O'KEEFE B J, BREYFOGLE L E, HILLMYERM A, et al. Mechanistic comparison of cyclic ester polymerizations by novel iron(III)-alkoxide complexes: Single vs multiple site catalysis[J]. J Am Chem Soc, 2002, 124: 4384-4393. [12] DROUIN F, OGUADINMA P O, WHITEHORNE T J J, et al. Lactide polymerization with chiral β-diketiminate zinc complexes[J]. Organometallics, 2010, 29: 2139-2147. [13] IKPO N, SAUNDERS L N, WALSH J L, et al. Zinc complexes of piperazinyl derived aminephenolate ligands: Synthesis, characterization and ring-opening polymerization activity[J]. Eur J Inorg Chem, 2011, 2011: 5347-5359. [14] WANG H, MAH. Highly diastereoselective synthesis of chiral aminophenolate zinc complexes and isoselective polymerization of rac-lactide[J]. Chem Commun, 2013, 49: 8686-8688. [15] ABBINA S, DUG. Zinc-catalyzed highly isoselective ring opening polymerization of rac-lactide[J]. ACS Macro Letters, 2014, 3: 689-692. [16] DUAN R, GAO B, LI X, et al. Zinc complexes bearing tridentate O,N,O-type half-Salen ligands for ring-opening polymerization of lactide[J]. Polymer, 2015, 71: 1-7. [17] CHANG C H, CHUANG H J, CHEN TY, et al. Di-nuclear zinc complexes containing tridentate imino benzotriazole phenolate derivatives as efficient catalysts for ring opening polymerization of cyclic esters and copolymerization of phthalic anhydride with cyclohexene oxide[J]. J Polym Sci, Part A: Polym Chem, 2016, 54: 714-725. [18] XIE H, MOU Z, LIUB, et al. Phosphinimino-amino magnesium complexes: Synthesis and catalysis of heteroselective ROP of rac-lactide[J]. Organometallics, 2014, 33: 722-730. [19] GHOSH S, ANTHARJANAM P K S, CHAKRABORTY D. Magnesium complexes of the N, O polydentate scaffold: Synthesis, structural characterization and polymerization studies[J]. Polymer, 2015, 70: 38-51. [20] HONRADO M, OTERO A, FERNNDEZ-BAEZAJ, et al. New racemic and single enantiopure hybrid scorpionate/cyclopentadienyl magnesium and zinc initiators for the stereoselective ROP of lactides[J]. Organometallics, 2015, 34: 3196-3208. [21] WANG Y, MA H. Aluminum complexes of bidentate phenoxy-amine ligands: Synthesis, characterization and catalysis in ring-opening polymerization of cyclic esters[J]. J Organomet Chem, 2013, 731: 23-28. [22] NORMAND M, ROISNEL T, CARPENTIER JF, et al. Dinuclear vs. mononuclear complexes: Accelerated, metal dependent ring-opening polymerization of lactide[J]. Chem Commun, 2013, 49: 11692-11694. [23] ZHAO N, WANG Q, HOU G, et al. Synthesis, structure, and catalytic activity of binuclear aluminum complexes with chiral biaryl-based N2O ligands[J]. J Organomet Chem, 2014, 754: 51-58. [24] PANG X, DUAN R, LI X, et al. Bimetallic Schiff base aluminum complexes based on pentaerythrityl tetramine and their stereoselective polymerization of racemic lactide[J]. RSC Adv, 2014, 4: 22561-22566. [25] PRESS K, GOLDBERG I, KOLM. Mechanistic insight into the stereochemical control of lactide polymerization by salan-aluminum catalysts[J]. Angew Chem Int Ed, 2015, 54: 14858-14861. [26] DUAN R, SUN Z, PANG X, et al. Non-symmetrical aluminium salen complexes: Synthesis and their reactivity with cyclic ester[J]. Polymer, 2015, 77: 122-128. [27] CHANG M C, LU W Y, CHANG HY, et al. Comparative study of aluminum complexes bearing N,O- and N,S-Schiff base in ring-opening polymerization of ε-caprolactone and l-lactide[J]. Inorg Chem, 2015, 54: 11292-11298. [28] KAN C, GE J, MA H. Aluminum methyl, alkoxide and α-alkoxy ester complexes supported by 6,6’-dimethylbiphenylbridged salen ligands: Synthesis, characterization and catalysis for rac-lactide polymerization[J]. Dalton Trans, 2016, 45: 6682-6695. [29] KO B T, LIN C C. Synthesis, characterization, and catalysis of mixed-ligand lithium aggregates, excellent initiators for the ring-opening polymerization of l-lactide[J]. J Am Chem Soc, 2001, 123: 7973-7977. [30] PENG Y L, HUANG Y, CHUANG H J, et al. Synthesis and characterization of biodegradable polylactides and polylactide-block-poly(Z-lysine) copolymers[J]. Polymer, 2010, 51: 4329-4335. [31] ZHANG J, JIAN C, GAO Y, et al. Synthesis and characterization of multi-alkali-metal tetraphenolates and application in ring-opening polymerization of lactide[J]. Inorg Chem, 2012, 51: 13380-13389. [32] HUANG Y, WANG W, LIN C C, et al. Potassium, zinc, and magnesium complexes of a bulky OOO-tridentate bis(phenolate) ligand: Synthesis, structures, and studies of cyclic ester polymerisation[J]. Dalton Trans, 2013, 42: 9313-9324. [33] ZHANG J, XIONG J, SUN Y, et al. Highly iso-selective and active catalysts of sodium and potassium monophenoxides capped by a crown ether for the ring-opening polymerization of rac-lactide[J]. Macromolecules, 2014, 47: 7789-7796. [34] LI Y, ZHAO H, MAO X, et al. Structures of potassium calix[4]arene crown ether inclusion complexes and application in polymerization of rac-Lactide[J]. Dalton Trans, 2016, 45: 9636-9645. [35] CHEN C, CUI Y, MAO X, et al. Suppressing cyclic polymerization for isoselective synthesis of high molecular-weight linear polylactide catalyzed by sodium/potassium sulfonamidate complexes[J]. Macromolecules, 2017, 50: 83-96. [36] PIETRANGELO A, KNIGHT S C, GUPTA A K, et al. Mechanistic study of the stereoselective polymerization of D,L-lactide using indium(III) halides[J]. J Am Chem Soc, 2010, 132: 11649-11657. [37] YU I, ACOSTA-RAMIREZ A, MEHRKHODAVANDI P. Mechanism of living lactide polymerization by dinuclear indium catalysts and its impact on isoselectivity[J]. J Am Chem Soc, 2012, 134: 12758-12773. [38] NORMAND M, DORCET V, KIRILLOV E, et al. {Phenoxy-imine}aluminum versus -indium complexes for the immortal ROP of lactide: Different stereocontrol, different mechanisms[J]. Organometallics, 2013, 32: 1694-1709. [39] ALUTHGE D C, PATRICK B O, MEHRKHODAVANDI P. A highly active and site selective indium catalyst for lactide polymerization[J]. Chem Commun, 2013, 49: 4295-4297. [40] DAGORNE S, NORMAND M, KIRILLOV E, et al. Gallium and indium complexes for ring-opening polymerization of cyclic ethers, esters and carbonates[J]. Coord Chem Rev, 2013, 257: 1869-1886. [41] KAPELSKI A, OKUDA J. Ring-opening polymerization of rac- and meso-lactide initiated by indium bis(phenolate) isopropoxy complexes[J]. J Polym Sci, Part A: Polym Chem, 2013, 51: 4983-4991. [42] MA H, SPANIOL T P, OKUDA J. Highly heteroselective ring-opening polymerization of rac-lactide initiated by bis(phenolato)scandium complexes[J]. Angew Chem Int Ed, 2006, 45: 7818-7821. [43] LIU X, SHANG X, TANGT, et al. Achiral lanthanide alkyl complexes bearing N,O multidentate ligands. Synthesis and catalysis of highly heteroselective ring-opening polymerization of rac-lactide[J]. Organometallics, 2007, 26: 2747-2757. [44] MOU Z, LIU B, LIU X, et al. Efficient and heteroselective heteroscorpionate rare-earth-metal zwitterionic initiators for ROP of rac-lactide: Role of σ-ligand[J]. Macromolecules, 2014, 47: 2233-2241. [45] HERMANS C, RONG W, SPANIOLT P, et al. Lanthanum complexes containing a bis(phenolate) ligand with a ferrocene-1,1’-diyldithio backbone: Synthesis, characterization, and ring-opening polymerization of rac-lactide[J]. Dalton Trans, 2016, 45: 8127-8133. [46] HAO H, BHANDARI S, DING Y, et al. Pyrrolylaldiminato complexes of Zn, Mg and Al[J]. Eur J Inorg Chem, 2010, 2002(5): 1060-1065. [47] KANEKO H, DIETRICH H M, SCHDLE C, et al. Synthesis of rare-earth-metal iminopyrrolyl complexes from alkyl precursors: Ln→Al N-ancillary ligand transfer[J]. Organometallics, 2013, 32: 1199-1208. [48] PRACHA S, PRABAN S, NIEWPUNG A, et al. Syntheses of bi(pyrrolylaldiminato)aluminum complexes for the polymerisation of lactide[J]. Dalton Trans, 2013, 42: 15191-15198. [49] TABTHONG S, NANOK T, KONGSAEREE P, et al. Monomethylaluminum and dimethylaluminum pyrrolylaldiminates for the ring-opening polymerization of rac-lactide: Effects of ligand structure and coordination geometry[J]. Dalton Trans, 2014, 43: 1348-1359. [50] YOSHIDA Y, MATSUI S, TAKAGIY, et al. New titanium complexes having two pyrrolide-imine chelate ligands: Syntheses, structures, and ethylene polymerization behavior[J]. Organometallics, 2001, 20: 4793-4799. [51] LI Y S, LI Y R, LI XF. New neutral nickel(II) complexes bearing pyrrole-imine chelate ligands: Synthesis, structure and norbornene polymerization behavior[J]. J Organomet Chem, 2003, 667: 185-191. [52] BROOMFIELD L M, WRIGHT J A, BOCHMANN M. Synthesis, structures and reactivity of 2-phosphorylmethyl-1H-pyrrolato complexes of titanium, yttrium and zinc [J]. Dalton Trans, 2009, 39:8269-8279. [53] XU B C, HU T,WU J Q, et al. Novel vanadium(III) complexes with bidentate N,N-chelating iminopyrrolide ligands: Synthesis, characterization and catalytic behaviour of ethylene polymerization and copolymerization with 10-undecen-1-ol[J]. Dalton Trans, 2009, 41:8854-8863. [54] GOMES C S, SURESH D, GOMES P T, et al. Sodium complexes containing 2-iminopyrrolyl ligands: The influence of steric hindrance in the formation of coordination polymers[J]. Dalton Trans, 2010, 39: 736-748. [55] LIU J Y, TAO P, WANG Y X, et al. Highly active half-sandwich chromium(III) catalysts bearing bis(imino)pyrrole ligands for ethylene (co)polymerization[J]. RSC Adv, 2014, 4: 19433-19439. [56] SAVEM, SCHAPPACHER M, SOUM A. Controlled ring-opening polymerization of lactones and lactides initiated by lanthanum isopropoxide, 1. general aspects and kinetics[J]. Macromol Chem Phys, 2002, 203: 889-899. [57] ROSCA S C, ROSCA D A, DORCET V, et al. Alkali aminoether-phenolate complexes: Synthesis, structural characterization and evidence for an activated monomer ROP mechanism[J]. Dalton Trans, 2013, 42: 9361-9375. [58] CLARKL, DEACON G B, FORSYTH C M, et al. Synthesis and structures of calcium and strontium 2,4-di-tert-butylphenolates and their reactivity towards the amine co-initiated ring-opening polymerisation of rac-lactide[J]. Dalton Trans, 2013, 42: 9294-9312. [59] CHEN H Y, MIALON L, ABBOUD K A, et al. Comparative study of lactide polymerization with lithium, sodium, magnesium, and calcium complexes of BHT[J]. Organometallics, 2012, 31: 5252-5261. [60] GALLEGOS C, TABERNERO V, GARCI-VALLE F M, et al. Synthesis and structure of homo- and heterometallic lithium-magnesium complexes and their reactivity in the ROP of rac-lactide[J]. Organometallics, 2013, 32: 6624-6627. [61] GARCIA'-VALLE F M, ESTIVILL R, GALLEGOS C, et al. Metal and ligand-substituent effects in the immortal polymerization of rac-lactide with Li, Na, and K phenoxo-imine complexes[J]. Organometallics, 2015, 34: 477-487. [62] DAI Z, SUN Y, XIONG J, et al. Simple sodium and potassium phenolates as catalysts for highly isoselective polymerization of rac-lactide[J]. Catal Sci Technol, 2016, 6: 515-520. [63] WU B B, WANG Z X. Crown ether complexes of potassium quinolin-8-olates: Synthesis, characterization and catalysis toward the ring-opening polymerization of rac-lactide[J]. RSC Adv, 2017, 7: 11657-11664.
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