脉冲激光沉积法制备Sb2S3薄膜太阳能电池

doi:10.3969/j.issn.0253-2778.2020.06.003

中国科学技术大学学报 ›› 2020, Vol. 50 ›› Issue (6): 733-737.DOI: 10.3969/j.issn.0253-2778.2020.06.003

脉冲激光沉积法制备Sb2S3薄膜太阳能电池

郑皓天，张立建，陈超，江国顺，陈涛，朱长飞

中国科学技术大学材料科学与工程系，安徽合肥 230026

收稿日期:2019-11-27 修回日期:2020-03-16 接受日期:2020-03-16 出版日期:2020-06-30 发布日期:2020-03-16
通讯作者: 朱长飞
作者简介:郑皓天，男，1993年生，硕士. 研究方向：太阳能电池. E-mail：dahan93@mail.ustc.edu.cn
基金资助:
中国科学技术大学重要方向项目培育基金(WK2060140024)资助.

Pulsed laser deposition derived Sb2S3 thin film for solar cell applications

ZHENG Haotian, ZHANG Lijian, CHEN Chao, JIANG Guoshun, CHEN Tao, ZHU Changfei

Department of Materials Science and Engineering，University of Science and Technology of China，Hefei 230026，China

Received:2019-11-27 Revised:2020-03-16 Accepted:2020-03-16 Online:2020-06-30 Published:2020-03-16

摘要/Abstract

摘要： 利用脉冲激光沉积法（PLD）制备出高质量的Sb2S3薄膜.通过改变沉积时间来调节Sb2S3薄膜的厚度，进而研究不同Sb2S3厚度对电池效率的影响.研究发现，当沉积时间为5 min时，Sb2S3太阳能电池效率达到最高，为3.98%.分析外量子效率和电化学阻抗谱发现，厚度的变化会影响Sb2S3层对光的吸收能力，同时也会增加光生载流子的非辐射复合，从而影响电池的效率.

关键词: 三硫化二锑, 脉冲激光沉积法, 薄膜, 太阳能电池

Abstract: High quality Sb2S3 thin films were prepared by pulsed laser deposition (PLD) method. The thickness of the Sb2S3 thin film was adjusted by changing the deposition duration to investigate the thickness dependent power conversion efficiency in complete solar devices. It was found that the Sb2S3 solar cell achieved power conversion efficiency of 3.98% when the deposition time was 5 min. Based on external quantum efficiency and electrochemical impedance spectroscopy analysis, it was observed that the change of thickness affects both the light harvesting capacity of the Sb2S3 layer and non-radiative recombination of photo generated carriers, thus affecting the efficiency of the solar cell.

Key words: Sb2S3, pulsed laser deposition, thin film, solar cells

中图分类号:

O484.1

郑皓天，张立建，陈超，江国顺，陈涛，朱长飞. 脉冲激光沉积法制备Sb2S3薄膜太阳能电池[J]. 中国科学技术大学学报, 2020, 50(6): 733-737.

ZHENG Haotian, ZHANG Lijian, CHEN Chao, JIANG Guoshun, CHEN Tao, ZHU Changfei. Pulsed laser deposition derived Sb2S3 thin film for solar cell applications[J]. Journal of University of Science and Technology of China, 2020, 50(6): 733-737.

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脉冲激光沉积法制备Sb2S3薄膜太阳能电池

Pulsed laser deposition derived Sb2S3 thin film for solar cell applications

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